Carbon and its Compounds
1. Bonding in Carbon – The Covalent Bond
- Atomic number of carbon = 6
- Electronic configuration → 2, 4 (4 valence electrons)
- Carbon cannot form ionic bonds easily (losing/gaining 4 electrons requires huge energy)
- Carbon forms covalent bonds by sharing electrons → achieves noble gas configuration
- Covalent compounds have:
- Low melting & boiling points
- Poor conductors of electricity (no free ions/electrons)
- Usually insoluble in water (except few like alcohols)
Electron dot structure examples:
- Methane (CH₄): Carbon shares 4 electrons with 4 H atoms
- Ethene (C₂H₄): Double bond between two C atoms
- Ethyne (C₂H₂): Triple bond between two C atoms
2. Versatile Nature of Carbon
Carbon forms more than 3 million compounds → due to two unique properties:
- Tetravalency: Carbon has 4 valence electrons → can form 4 covalent bonds
- Catenation: Ability to form long chains, branches & rings by bonding with other carbon atoms (C–C bond is very strong & stable)
Other reasons: Small size of carbon atom, Ability to form single, double & triple bonds.
Allotropes of Carbon:
- Diamond: Hardest natural substance, bad conductor, used in cutting tools & jewellery
- Graphite: Soft, slippery, good conductor (used in pencils & electrodes)
- Fullerenes: e.g., Buckminsterfullerene (C₆₀) – football-shaped
- Graphene: Single layer of graphite (very strong & conductor)
3. Saturated and Unsaturated Carbon Compounds (Hydrocarbons)
| Type | Bonds | General Formula | Example | Reactivity |
|---|---|---|---|---|
| Saturated | Only single C–C bonds | CₙH₂ₙ₊₂ | Methane (CH₄), Ethane (C₂H₆) | Less reactive |
| Unsaturated | At least one double/triple bond | — | — | More reactive |
- Alkanes (saturated): CₙH₂ₙ₊₂ (e.g., CH₄, C₂H₆, C₃H₈)
- Alkenes (unsaturated, one double bond): CₙH₂ₙ (e.g., Ethene C₂H₄)
- Alkynes (unsaturated, one triple bond): CₙH₂ₙ₋₂ (e.g., Ethyne C₂H₂)
4. Chains, Branches and Rings
- Straight chain: e.g., n-Pentane (C₅H₁₂)
- Branched chain: e.g., Isopentane, Neopentane (isomers)
- Ring (cyclic): e.g., Cyclohexane (C₆H₁₂), Benzene (C₆H₆ – aromatic)
5. Homologous Series
A series of organic compounds having the same functional group and similar chemical properties, but successive members differ by –CH₂– unit (14 u in molecular mass).
Characteristics: Same general formula, similar chemical properties, gradual change in physical properties (boiling point increases with chain length).
Example: Alcohols: CH₃OH (Methanol) → C₂H₅OH (Ethanol) → C₃H₇OH (Propanol) ...
6. Functional Groups & Nomenclature (IUPAC)
| Functional Group | Formula | Suffix/Prefix | Example |
|---|---|---|---|
| Alkane | — | –ane | Methane |
| Alkene | C=C | –ene | Ethene |
| Alkyne | C≡C | –yne | Ethyne |
| Alcohol | –OH | –ol | Ethanol (C₂H₅OH) |
| Aldehyde | –CHO | –al | Ethanal (CH₃CHO) |
| Ketone | >C=O | –one | Propanone (CH₃COCH₃) |
| Carboxylic acid | –COOH | –oic acid | Ethanoic acid (CH₃COOH) |
| Halogen | –X (Cl,Br,I) | Prefix: chloro/bromo | Chloromethane (CH₃Cl) |
7. Chemical Properties of Carbon Compounds
- Combustion: CH₄ + 2O₂ → CO₂ + 2H₂O + heat & light
- Oxidation: Ethanol → Ethanoic acid (using alkaline KMnO₄)
- Addition reaction: Ethene + H₂ → Ethane (Ni catalyst, heat) - used in hydrogenation of oils
- Substitution reaction: CH₄ + Cl₂ → CH₃Cl + HCl (in sunlight)
8. Some Important Carbon Compounds
A. Ethanol (C₂H₅OH)
Colourless, pleasant smell, volatile liquid. Reactions include combustion, reaction with Na (H₂ gas), and dehydration to Ethene.
B. Ethanoic acid (CH₃COOH)
Sour taste, turns blue litmus red. 5-8% solution is Vinegar. Reactions include esterification and reaction with NaHCO₃ (CO₂ effervescence).
9. Soaps and Detergents
- Soap: Sodium/potassium salt of long-chain fatty acids.
- Structure: Hydrophilic head (water loving) and Hydrophobic tail (oil loving).
- Cleansing: Micelle formation emulsifies dirt.
| Feature | Soap | Detergent |
|---|---|---|
| Source | Natural (fats/oils) | Synthetic (petroleum) |
| In hard water | Forms scum | No scum |
| Biodegradability | Biodegradable | Some are non-biodegradable |
MCQs: Carbon and its Compounds
- Which of the following is the correct electronic configuration of carbon?
- 2, 8
- 2, 4
- 2, 6
- 2, 8, 2
Ans: B) 2, 4 - The property of carbon atoms due to which they can form long chains and rings is called:
- Tetravalency
- Catenation
- Isomerism
- Allotropy
Ans: B) Catenation - Which of the following is an unsaturated hydrocarbon?
- Ethane
- Propane
- Ethene
- Butane
Ans: C) Ethene - The general formula of alkynes is:
- CₙH₂ₙ₊₂
- CₙH₂ₙ
- CₙH₂ₙ–2
- CₙHₙ
Ans: C) CₙH₂ₙ–2 - Which functional group is present in ethanol?
- –CHO
- –COOH
- –OH
- >C=O
Ans: C) –OH - The compound formed when ethanol reacts with sodium metal is:
- Sodium ethoxide + Hydrogen
- Sodium acetate + Hydrogen
- Ethene + Hydrogen
- Ethanoic acid + Sodium
Ans: A) Sodium ethoxide + Hydrogen - Which of the following reactions is shown only by unsaturated hydrocarbons?
- Substitution reaction
- Addition reaction
- Combustion reaction
- Oxidation reaction
Ans: B) Addition reaction - The catalyst used in hydrogenation of vegetable oils is:
- Fe
- Ni
- Pt
- Pd
Ans: B) Ni - Which allotrope of carbon is used as a lubricant?
- Diamond
- Graphite
- Fullerene
- Coke
Ans: B) Graphite - The IUPAC name of CH₃–CH=CH–CH₃ is:
- Butane
- Butene
- But-2-ene
- But-1-ene
Ans: C) But-2-ene - Which of the following compounds is formed when ethanoic acid reacts with ethanol in presence of conc. H₂SO₄?
- Ethyl ethanoate
- Ethene
- Methane
- Sodium ethanoate
Ans: A) Ethyl ethanoate - The gas evolved when ethanoic acid reacts with sodium bicarbonate is:
- Hydrogen
- Oxygen
- Carbon dioxide
- Nitrogen
Ans: C) Carbon dioxide - Which of these will form scum when used with hard water?
- Detergent
- Soap
- Both soap and detergent
- Neither soap nor detergent
Ans: B) Soap - The structural formula of a compound having molecular formula C₄H₁₀ is:
- CH₃–CH₂–CH=CH₂
- CH₃–CH₂–CH₂–CH₃
- CH₃–C≡C–CH₃
- CH₂=CH–CH₂–CH₃
Ans: B) CH₃–CH₂–CH₂–CH₃ - Which of the following is a homologous series?
- CH₄, C₂H₄, C₃H₆
- CH₃OH, C₂H₅OH, C₃H₇OH
- CH₃Cl, C₂H₅Cl, C₃H₇Cl
- Both B and C
Ans: D) Both B and C - The product formed on complete oxidation of ethanol is:
- Ethene
- Ethanoic acid
- Methane
- Carbon monoxide
Ans: B) Ethanoic acid - Buckminsterfullerene is an allotrope of carbon having the formula:
- C₆
- C₆₀
- C₇₀
- C₁₂
Ans: B) C₆₀ - Which type of reaction is: CH₄ + Cl₂ → CH₃Cl + HCl (in sunlight)?
- Addition
- Substitution
- Esterification
- Oxidation
Ans: B) Substitution - The micelle formation in soap solution helps in:
- Making water soft
- Removing dirt and grease
- Increasing boiling point
- Decreasing surface tension only
Ans: B) Removing dirt and grease - Which of the following compounds has a –COOH functional group?
- Methanol
- Ethanal
- Methanoic acid
- Propanone
Ans: C) Methanoic acid



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